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FerdiEgb Experienced User
Joined: 10 Aug 2008 Posts: 111 Location: Stabroek, Belgium
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Posted: 13 Apr 2009 10:26 pm Post subject: |
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| Richard111 wrote: | | It appears the global rise of CO2 is equal in both hemispheres yet most human produced CO2 is in the NH. What is producing the "extra" CO2 in the SH? |
That is what Tom Quirk says, based on the assumption (based on a model!) that there is no lag in CO2 levels between the SH and the NH. But if you look at the real measurements (yes Derek...), there is a lag of over 12 months between Mauna Loa and the south pole measurements!
See: http://www.ferdinand-engelbeen.be/klimaat/klim_img/co2_trends_1995_2004.jpg
Tom Quirk's method to detect a lag was only looking at +/- 6 month lags, but any lag + a multiple of 12 months gives the same result. Thus he is completely wrong that the SH is an extra source (the equatorial waters are a source, but the total SH acts as a sink). The NH is clearly the source of the increase of CO2 levels and the decrease of d13C:
http://www.ferdinand-engelbeen.be/klimaat/klim_img/d13c_trends.jpg
(all stations ordered from N to S) |
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FerdiEgb Experienced User
Joined: 10 Aug 2008 Posts: 111 Location: Stabroek, Belgium
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Posted: 13 Apr 2009 10:43 pm Post subject: |
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| Derek wrote: | | FerdiEgb wrote: | | Again, sorry to disappoint you -again- in what you like to hear... Trees are actually CO2 sinks. At one side, humans are cutting forests, mainly in the tropics, but at the other side we are replanting forests in the mid-latitudes in North America and Europe. The balance still is negative, but that is added to the human emissions, as that is human induced. |
I thought the UN had to recently alter their position about tropical rain forest.
In actual fact satelites show there is more rain forest,
because humans have been abandoning life in the forests and moving to the cities.
The opposite of what is suggested above.
The arguements revolved around whether the forest was "virgin" or not, so supposedly effecting species counts,
but the main point was not disputed (because satelites had shown it to be the case)
there is more rain forest, because humans (net) have been abandoning the forests.
I wonder if such an obvious and large discrepancy could effect your guesstimates and plots. ? |
Derek, I haven't looked recently at the forest balances, and I wonder if it is true. but let's assume that there is a balance, thus as much added than destroyed by humans.
That would imply that the emissions are 1-2 GtC/year (0.5-1 ppmv/yr) less and only contain pure fossil fuel burning. That means that a larger portion of the emissions stays (longer) in the atmosphere (less sinks in vegetation) and that in some peak years (1973, 1988, 1998) the increase is not only from the emissions, but a part also comes from ocean warming. But the bulk of the increase still is from the emissions and the oceans still act as overall sinks. |
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Lucy Skywalker Site Admin

Joined: 09 May 2006 Posts: 535 Location: Somerset, UK
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Posted: 14 Apr 2009 06:59 am Post subject: |
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Ferdinand,
thanks for all your hard work! Just when the discussion was getting interesting I could not get online! I'm going to deal with Quirk first.
I read through the whole thread at WUWT. This was a very interesting experience. I gleaned a lot. Ferdinand, you've been pursuing not just me but also Richard Courtney, Allan MacRae, and Tom Quirk (all around the globe for his sins, he says!). And I'm not sure that any of us feel we can disagree with you totally. It really feels like science at the cutting edge, where one gets inspired to look further. In this spirit, I did another appraisal that gathers and adds to the wisdom of other posters:
MULTIPLE SOURCES OF CO2:
(1) slow ongoing recovery from LIA - warming oceans outgassing on balance [longterm effects still working]
(2) recent warming - warming oceans outgassing on balance [overall recent picture]
(3) ocean currents reaching tropics [local picture]
(4) ongoing loss of forests - 2.5 m sq miles to 1.5 m
(5) fossil fuels burning
(6) sea ice formation @ Antarctica
(7) population
(8 ) soil in formation
(9) volcanoes
(10) extra-terrestrial sources - may sound silly but I've seen evidence that deserves to be taken seriously
MULTIPLE SINKS OF CO2:
(1) currents in polar oceans - cool ocean absorbs, huge potential
(2) cloud & rain - huge surface area 300,000 times that of the oceans (or more?)
(3) leafy biosphere - huge surface area
(4) soil in formation - huge, virtually uncatalogued
(5) ocean - phytoplankton - huge
(6) ocean - coral, shellfish & fishes in CaCO2 compounds
(7) ocean floor deposit
(8 ) sea ice loss @ Arctic Ocean # increasing NS diff of ppm
I do not know quantities here - some may be tiny, others may be important and neglected. I just looked for obvious things possibly forgotten, because I think the picture may be more complex than people usually consider.
Ferdinand, I still think you underestimate the power of the natural flux, and the possibility of a surplus at present for reasons other than, or in addition to, fossil fuel, of which temperature is just one. Forests: I read yesterday the global area is down overall, plus some say it's regrowing - I need hard data - but I suspect overall loss that could impinge the CO2 level. This suspicion is heightened by Lansner's recent evidence showing how BADLY the trees mis-measure the MWP temperature - which I and others suspect may be because there were far more forests then, so CO2 was lower - and pines in particular (remember the bristlecone pines?) are sensitive to CO2 levels
Unfortunately, I now have a huge disadvantage. I cannot read Quirk's original to see the diagrams & details. Not unless I pay subscription. Or can you help? For without all that DATA, I cannot judge adequately as to whether your criticisms are valid or not. Yet I have the funny feeling I did see more originally, that gave me confidence to say he was right. Where? Anyway, here's quoting from your comments at WUWT:
could you explain please, in simple terms, what's this oxygen balance, and is the paper well-received by other skeptics? because, sad to say, this for me is now a mark of the trustworthiness of any paper since all peer-reviewed material has to doff cap to AGW and some is distinctly skewed in the direction of illegitimately proving it.
| Quote: | | "all other possible sinks being much too slow" | what other sinks?
| Quote: | | "Thus both the biosphere and the oceans are net sinks for CO2 and can’t be the cause of the CO2 increase of the atmosphere." | Not so. Just because you pay money into your bank does not mean your bank cannot pay you money. By Henry's Law, 49/50th of our emissions should be dissolved in the oceans, all other things being equal. Therefore since CO2 is rising, it would seem that it has to be from other factors.
| Quote: | "The main problem is in figure 9: The correlation between ENSO and d13C variability is relative good, but that only means that ENSO (in part) is responsible for the variability around the trend, not the trend itself! The same jumping to (wrong) conclusions was made by others, comparing temperature trends with the variability of the year by year increase of CO2: these have a quite good correlation, as there is a short term response of CO2 increase speed to temperature changes, but only a small influence of temperature on the CO2 trend itself. Thus temperature is not the cause of the increase of CO2 in the atmosphere, neither is temperature (or ENSO events) the cause of the d13C decrease.
Have a look at the difference in appearance between looking at the variability of d13C on itself and the variability of d13C around the trend:
http://www.ferdinand-engelbeen.be/klimaat/klim_img/d13c_var_trend.gif " | I understand what you're saying here and agree, but without Quirk's data I cannot / will not comment on his take.
But the interesting point, what IMHO is the clincher, I leave to the next-but-one post... First, a discussion of Segalstad and the isotopes... |
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Lucy Skywalker Site Admin

Joined: 09 May 2006 Posts: 535 Location: Somerset, UK
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Posted: 14 Apr 2009 07:46 am Post subject: |
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Here we go Ferdinand, let's look at Segalstad.
You must read Segalstad direct, at the very least the section in question http://www.greenworldtrust.org.uk/Science/Scientific/Segalstad.htm#10 In this section we find these words:
| Quote: | | This atmospheric CO2 delta-13-C mixing value of -11 permil to be expected from IPCC's model is not found in actual measurements. Keeling et al. (1989) reported a measured atmospheric delta-13-C value of -7.489 permil in December 1978, decreasing to -7.807 permil in December 1988 (the significance of all their digits not justified). These values are close to the value of the natural atmospheric CO2 reservoir, far from the delta-13-C value of -11 permil expected from the IPCC model. | I note two crucial pieces of evidence.
(1) The IPCC "mixing" allows 21% anthropogenic (this is what Segalstad uses for his calculations) but the Mauna Loa figure http://scrippsco2.ucsd.edu/graphics_gallery/mauna_loa_record/mauna_loa_seas_adj_fossil_fuel_trend.html is 57% - close to your own 56%.
(2) Your own excellent graph http://www.ferdinand-engelbeen.be/klimaat/klim_img/d13c_var_trend.gif shows a decline, as you said, from -7.6 permil on the PDB scale to -8.0 permil, from 1961 to 2001. This seems to tally with Segalstad's figures for 1978-88 above. But it does NOT tally with the level expected by even 21% anthropogenic CO2, let alone the 45%-53% I measured on the MLO graph, still less the 57% anthropogenic inclusion that MLO actually claim. It misses the level expected for even 21% anthropogenic inclusion, by a large amount. It misses MLO's claim of 57% and your claim of 56% by a huge amount. IT IS FAR CLOSER TO NATURAL, just as Segalstad maintains.
That seems to scupper the isotope evidence claiming to support a large anthropogenic inclusion.
Now further in defence of Segalstad, I've noted the following:
(1) huge list of studies re. CO2 lifetime ~6 years in air (see table in section 9 of his page)
(2) own study on 12C / 13C isotope balance re. lifetime (1992 - see table)
(3) good knowledge of sea - remembers Henry's Law
(4) ditto CO2 - remembers solubility
(5) ditto ice - Norwegian with knowledgeable tradition
(6) awareness of IPCC bias & false science - CO2 "buffer" factor
(7) awareness of IPCC bias & false science - ice core problems
(8 ) all these points add up to expertise - not to be set aside lightly.
Lastly, some possible reasons for the recent increase of 12C over 13C. Just my thoughts, inspired also by the WUWT posters:-
Warming oceans fractionally distil more 12C
Hungry phytoplankton with C4 metabolism fix on 13C (Julian Flood WUWT 01:23:52)
Chromium & zinc starved (no volcanoes) phytoplankton get C4 metab. (JF)
More dust --> silica to oceans --> diatoms with C4 metabolism (JF)
Fossil fuels add 12C (OR DO THEY?? - I'd like a check on the 12C / 13C levels of all of them, with average and range)
I'd go for warming oceans myself since from your other graph http://www.ferdinand-engelbeen.be/klimaat/klim_img/sponges.gif I see the 12C proportion starting to increase from end-of-LIA time. |
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Lucy Skywalker Site Admin

Joined: 09 May 2006 Posts: 535 Location: Somerset, UK
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Posted: 14 Apr 2009 08:04 am Post subject: |
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Right, now we've cleared the issues (1) what Quirk reveals or doesn't reveal (2) how Segalstad cuts through all that and gets to the heart of the matter ie the changing 13C level does NOT reveal an anthropogenic signature.
Let's have fun and look at what I think may be at work. First I want to use your own graph Ferdinand because it's very revealing if we note the growing differential between North Pole (Barrow @ 71ºN) and South Pole
because, allowing that CO2 follows temperature, this exactly mirrors what Alan Cheetham noticed http://www.appinsys.com/GlobalWarming/EarthMagneticField.htm which fits with Svensmark as well (Antarctica cooling). Steig's work proclaiming a "warming" Antarctica is, sadly, rubbish, just trying to make data fit warmists' beliefs, you can check that out with me here http://www.greenworldtrust.org.uk/Science/Scientific/babyIce.htm#antarctic or at Climate Audit.
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Lucy Skywalker Site Admin

Joined: 09 May 2006 Posts: 535 Location: Somerset, UK
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Posted: 14 Apr 2009 09:10 am Post subject: |
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Lastly, my recent observations, now we've sorted out the isotope data.
I think we've got problems with the MLO data.
I wasn't happy with the Mauna Loa graph http://scrippsco2.ucsd.edu/graphics_gallery/mauna_loa_record/mauna_loa_seas_adj_fossil_fuel_trend.html showing such an incredibly close fit between emissions and atmospheric CO2 rise. Finally I found the graph of CO2 emissions from fossil fuel.
http://www.earthpolicy.org/Indicators/CO2/2008_CO2 Emissions 1950-2006.GIF (you need to copy and paste this whole line up to GIF)
I measured exactly from the graph, what the tonnage of emissions was for 1964 and 2004. I've converted these figures by the approximation 2 gigatons C = 1 ppm CO2. It doesn't matter that this is approximate, as I wanted to compare 1964 and 2004. These years worked out neatly in round figures, 1.5 ppm and 4.0 ppm, near enough.
Then I returned to the Mauna Loa graph, and in Photoshop I used the "crop tool preview" to catch exactly the 10-year bands on the x-axis around 1964 and 2004, using Screen Print. I then adjusted the "crop tool preview" to show exactly where the bands cut the y-axis, to measure their width in ppm CO2. Mauna Loa states that they use a fixed fraction of 57% of all emissions. But if the graph really showed the fossil fuel trend as this fixed fraction of 57%, then each year would show a slope of 57% of that year's CDIAC record of fossil fuel emissions. But in 1964, the annual CO2 rise (the slope of the graph) is 0.8 ppm/yr; this represents 53% of that year's total CO2 emissions. And in 2004 the annual CO2 rise is similarly 1.8 ppm/yr; this represents 45% of that year's CO2 emissions.
The annual rate of fossil fuels emissions has almost trebled in this time period. This means a cumulative graph will have an end slope nearly three times as steep as the start slope. But the MLO graph does not steepen by this amount, it falls flat by an amount well in excess of any cumulative measuring errors. The cumulative emissions curve can only have been fitted to the CO2 curve by calibrating it on a sliding/logarithmic/whatever scale. This gives a false impression of fit. If the cumulative emissions is calibrated to fit the slope in 1964, it would rise steeply above the atmospheric graph in 2004; if it were calibrated to fit the slope in 2004, it would be far too high in 1964. So I cannot see that MLO's claim even fits their own graph. It seems less likely that CDIAC/BP is mistaken, since they have no agenda here.
I'd be delighted if anyone can check this, preferably with figures. But you can already see the misfit from the graphs. But as we realize from the previous 3 posts, the MLO curve cannot possibly be about an anthropogenic input anyway. |
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FerdiEgb Experienced User
Joined: 10 Aug 2008 Posts: 111 Location: Stabroek, Belgium
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Posted: 14 Apr 2009 02:44 pm Post subject: |
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| Lucy Skywalker wrote: | Here we go Ferdinand, let's look at Segalstad.
You must read Segalstad direct, at the very least the section in question http://www.greenworldtrust.org.uk/Science/Scientific/Segalstad.htm#10 In this section we find these words:
| Quote: | | This atmospheric CO2 delta-13-C mixing value of -11 permil to be expected from IPCC's model is not found in actual measurements. Keeling et al. (1989) reported a measured atmospheric delta-13-C value of -7.489 permil in December 1978, decreasing to -7.807 permil in December 1988 (the significance of all their digits not justified). These values are close to the value of the natural atmospheric CO2 reservoir, far from the delta-13-C value of -11 permil expected from the IPCC model. | I note two crucial pieces of evidence.
(1) The IPCC "mixing" allows 21% anthropogenic (this is what Segalstad uses for his calculations) but the Mauna Loa figure http://scrippsco2.ucsd.edu/graphics_gallery/mauna_loa_record/mauna_loa_seas_adj_fossil_fuel_trend.html is 57% - close to your own 56%.
(2) Your own excellent graph http://www.ferdinand-engelbeen.be/klimaat/klim_img/d13c_var_trend.gif shows a decline, as you said, from -7.6 permil on the PDB scale to -8.0 permil, from 1961 to 2001. This seems to tally with Segalstad's figures for 1978-88 above. But it does NOT tally with the level expected by even 21% anthropogenic CO2, let alone the 45%-53% I measured on the MLO graph, still less the 57% anthropogenic inclusion that MLO actually claim. It misses the level expected for even 21% anthropogenic inclusion, by a large amount. It misses MLO's claim of 57% and your claim of 56% by a huge amount. IT IS FAR CLOSER TO NATURAL, just as Segalstad maintains.
That seems to scupper the isotope evidence claiming to support a large anthropogenic inclusion.
Now further in defence of Segalstad, I've noted the following:
(1) huge list of studies re. CO2 lifetime ~6 years in air (see table in section 9 of his page)
(2) own study on 12C / 13C isotope balance re. lifetime (1992 - see table)
(3) good knowledge of sea - remembers Henry's Law
(4) ditto CO2 - remembers solubility
(5) ditto ice - Norwegian with knowledgeable tradition
(6) awareness of IPCC bias & false science - CO2 "buffer" factor
(7) awareness of IPCC bias & false science - ice core problems
(8 ) all these points add up to expertise - not to be set aside lightly.
Lastly, some possible reasons for the recent increase of 12C over 13C. Just my thoughts, inspired also by the WUWT posters:-
Warming oceans fractionally distil more 12C
Hungry phytoplankton with C4 metabolism fix on 13C (Julian Flood WUWT 01:23:52)
Chromium & zinc starved (no volcanoes) phytoplankton get C4 metab. (JF)
More dust --> silica to oceans --> diatoms with C4 metabolism (JF)
Fossil fuels add 12C (OR DO THEY?? - I'd like a check on the 12C / 13C levels of all of them, with average and range)
I'd go for warming oceans myself since from your other graph http://www.ferdinand-engelbeen.be/klimaat/klim_img/sponges.gif I see the 12C proportion starting to increase from end-of-LIA time. |
Hi Lucy, point by point:
The figures which are given by Segalstad are right, but the interpretation by Segalstad is wrong. And no IPCC model says that one must find -11 per mil d13C in the atmosphere, as no model expects that all low 13C carbon from the emissions still is in the atmosphere after 150 years (150/800 is replaced by higher d13C CO2 from other reservoirs every year). Thus Segalstad is attributing his own wrong assumptions to the IPCC.
The d13C ratio of the deep oceans is about zero per mil d13C, of the upper oceans +1 to +5 per mil (see the pre-industrial values for the Carribean sponges). There is a two-way fractionation between the ocean's surface and the atmosphere, which gives a drop in d13C level of about -8 per mil, thus any release of CO2 willhave a d13C level in the atmosphere somewhere from -8 (deep ocean) to -3 (ocean surface) per mil d13C.
Thus in total: any real addition of CO2 from the oceans will (slightly) INcrease the d13C level of the atmosphere, while we see a DEcrease. This effectively excludes the oceans as main source of the increase of CO2! The d13C level of the oceans is simply too high...
Rests some other possibilities (besides vegetation, see in a later message):
- The low d13C from the emissions is diluted by an extra amount released from the oceans.
But that means that over 10 times more CO2 need to be added by the oceans each year to dilute the d13C drop to the values which are observed, or an extra addition of 90 GtC/yr or 45 ppmv/yr. That is not what is seen in the atmosphere: it is only 1-2 ppmv/yr.
- The low d13C from the emissions is diluted by the seasonal exchanges between the atmosphere and the oceans (+vegetation).
No problem with that: the ocean exchange (partly from the ocean surface, partly from the deep oceans) has a higher d13C content than the current atmosphere, even after fractionation. In pre-industrial times the equilibrium was at -6.4 +/- 0.2 per mil d13C for the atmosphere (see the sponges record 1400-1850: http://www.ferdinand-engelbeen.be/klimaat/klim_img/sponges.gif ). Ice core records give a change in atmospheric d13C over the whole Holocene (last 10,000 years) of not more than 0.2 per mil d13C. The drop of 1.6 per mil d13C since 1850 is thus clearly different from temperature changes and can't be caused by the oceans.
The influence of upper oceans and vegetation exchanges is rather limited in that sense that any exchange is for a large part two ways out: any decrease in atmospheric d13C will decrease the d13C of the upper oceans and vegetation, but a part of that will return next year from the same ocean surface and rotting vegetation. The d13C decrease is only more spread over larger carbon reservoirs
The deep ocean circulation (THC) is of more interest: what is absorbed at the poles will not return next year but that may take 800 years and more. Thus what is going down at the poles reflects the composition of the current atmosphere (with some fractionation) and what gets out at the equator still has the (d13C) composition of CO2 of 800 years ago. And that is interesting. It is easy to calculate the amounts of deep ocean exchange necessary to dilute the fossil fuel low d13C to what is observed:
As you can see, the -11 per mil d13C indeed is right, if all human emissions still were in the atmosphere, but any exchange with the higher per mil d13C of the deep oceans will dilute the "human fingerprint". In this case an exchange of about 40 GtC/yr with the deep oceans will do the job... The real exchange with the oceans (deep + surface) is about 100 GtC/yr, thus 40 GtC/yr from/to the deep oceans may be quite right.
To be emphasized: this doesn't imply any real net addition from the oceans, only a lot of exchange!
For the rest of the remarks from Segalstad:
(1) As already said: all these studies are about the residence time fo individual molecules CO2, not the slightest connection with the speed that an excess amount is mass is reduced.
I'll try to give a money example: You start the day in your shop with 500 euro of which 200 are from Germany, the rest from other European countries. During the day, you have had a lot of transactions. At the end of the day you have lost 10 euro (2%) and you find only 100 German euro in your cash register (50% loss). Next day you add 20 non-German euro to your cash, same scenario: you end the day with 10 euro loss and about halve the German euro count. The German euro dilution is what the Segalstad studies show (50% loss in ratio over 5 years), the increase in mass (0.5-1% per year) is what your cash register shows as total amount of money at the end of the day, thanks to your daily additions (or you should have had a loss each day!)...
(2) see (1)
(3) there is a difference between amounts in seawater and fresh water (far more CO2 in seawater) and one need to take into account the (rather low) exchange speed, the pressure differences water-air, the influence of biolife in the oceans and the opposite actions of oceans and vegetation over the seasons/temperature...
(4) solubility is less relevant, pressure difference and exchange speed is far more relevant.
(5)-( Segalstad/Jaworowski declares items about ice cores which are completely outdated by more "recent" (1994!) literature, physically impossible and they show a complete lack of knowledge of a difference between age of the gas bubbles and the ice at the same depth! Sorry, but the misconceptions are such obvious, simply by reading the original works, one can see that the bias is at Segalstad's side...
Further your own additions:
- Even C4 plants add to the 13C level in the oceans/atmosphere, as these show lower d13C levels than the atmosphere. See:
http://homepage.mac.com/uriarte/carbon13.html
- An overview of d13C levels of different fuels and more in-depth explanation can be found at: http://www.barrettbellamyclimate.com/page34.htm |
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FerdiEgb Experienced User
Joined: 10 Aug 2008 Posts: 111 Location: Stabroek, Belgium
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Posted: 14 Apr 2009 08:50 pm Post subject: |
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Dear Lucy,
About the difference between MLO (NH) and SPO (SH) in CO2 increase rate...
Someone else did make the same remark: the SH is more ocean than the NH and thus warms up more slowly thus there is less release of CO2 in the SH, and still the oceans are the cause of the increase...
Besides the facts that the oceans are net sinks for CO2 outside the equator and that the d13C level is too high, this reasoning doesn't fit if you look at the temperature trends of the NH and the SH.
The split trends of the NH and SH can be found at:
http://data.giss.nasa.gov/gistemp/graphs/Fig.B.lrg.gif
It doesn't matter that GISS is less reliable than the others, as it is about the NH-SH differences in trend in this case:
The MLO data started in 1959, the SPO in 1958. In the period up to 1975, the NH shows a cooling, the SH a warming and after 1975 both show a warming, but the NH much faster. That means that the SPO measurements should show a faster increase up to 1975 than the MLO data (the latter even no increase at all or a decrease). But there is no influence of the different temperature profiles visible in the CO2 trend: MLO leads with increasing lag for SPO. Thus temperature is not the reason of the lag:
If one compares the accumulation trends between emissions and increase in the atmosphere:
again it is clear that the source is in the NH and that human emissions are to blame... |
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Lucy Skywalker Site Admin

Joined: 09 May 2006 Posts: 535 Location: Somerset, UK
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Posted: 15 Apr 2009 07:57 am Post subject: |
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Hi Ferdinand, dang! you floored me again. I need more time on this and I've got other things pressing now. But I'll be back to it, you know me.
(1) I haven't properly understood what you wrote about the dC13 calculations, though I've grasped the point you made about the high annual exchange masking the human input and shedding doubt on Segalstad's figure of 11. However, I need to understand this better; some of your details I did not understand; I think I want to be able to handle the PDB figures and check the calculations myself; when I understand this a bit better I'd like to go back to Segalstad to check out with him. I'm still not convinced he's totally wrong (but I need to do my homework!)
(2) We're in hot political area here. That means I need to know the bias of the authors of each relevant paper! I'd like to grasp the fractionation issue better. I seem to remember Segalstad had his doubts. It certainly seems to me that the sea HAS to release proportionally more 12C... more homework! I don't see how you can say you've proven the sea is not the source of the extra CO2 on these grounds, when it has been for so long exchanging huge quantities of CO2, annually far in excess of either our emissions or the recent increase. You say that over 10 times the amount of CO2 needs to be added by the oceans to dilute the d13C drop we are witnessing; but supposing this is upside down? supposing that the lower 13C is precisely BECAUSE the oceans are warmer and therefore even more efficient at fractionating?
(3) When you answered my points 5-8 about Segalstad, your language plus lack of actual evidence makes you sound like the warmists. With this darned climate science, more recent papers do not necessarily do better science than older papers. And Segalstad's collection of papers that show the time CO2 is in the atmosphere to be far less than IPCC want, still hold. And as for there being two different kinds of measurement of CO2 "residence", that sounds like the worst kind of wool-pulling. I need to go back to grasp those notions or non-notions as the case may be. You might be right. But so far I'm not convinced!
(4) your photos of the different temperature trends for NH, EQ and SH do not, for me prove your point: they prove mine, that the SH with the higher ocean content is a truer reflection of the steady (inertia-effect) ongoing warming of the oceans that reflects in the steady CO2 rise. Mixing time is sufficient IMO. But again, I need to look at it carefully.
(5) you haven't even considered the extraordinary fit between my two pictures: local temp anomalies worldwide, and CO2 differential rise
(6) nor have you answered the MLO record issues. Nor have you given me access to understanding the diagrams from Quirk.
However, (5) and (6) could be because enough was enough for the time being! and I need to do more homework. Ferdinand, you are hot on this case, following everyone around with your points! Do you know, therefore, who you've had dealings with, who might be most able to help me understand the d13C maths and fractionation experiments and proof? Because I've yet to be convinced that those were done without AGW bias, and though I'm also willing to be convinced, I'd like contact with anyone non-AGW who understands the isotope intricacies.
Enough for now! Cheers  |
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FerdiEgb Experienced User
Joined: 10 Aug 2008 Posts: 111 Location: Stabroek, Belgium
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Posted: 15 Apr 2009 11:01 am Post subject: |
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| Lucy Skywalker wrote: | Hi Ferdinand, dang! you floored me again. I need more time on this and I've got other things pressing now. But I'll be back to it, you know me.
(2) We're in hot political area here. That means I need to know the bias of the authors of each relevant paper! I'd like to grasp the fractionation issue better. I seem to remember Segalstad had his doubts. It certainly seems to me that the sea HAS to release proportionally more 12C... more homework! I don't see how you can say you've proven the sea is not the source of the extra CO2 on these grounds, when it has been for so long exchanging huge quantities of CO2, annually far in excess of either our emissions or the recent increase. You say that over 10 times the amount of CO2 needs to be added by the oceans to dilute the d13C drop we are witnessing; but supposing this is upside down? supposing that the lower 13C is precisely BECAUSE the oceans are warmer and therefore even more efficient at fractionating? |
Hi Lucy,
Warmer oceans mean that more of the heavy isotope would be released from the oceans. I have no figures for d13C, but it is the case for d18O anyway. That is used to reconstruct the ocean temperatures of the past. In the case of the Holocene, including the MWP and the LIA don't show more than 0.2 per mil d13C in ice cores, sediments and coralline sponges (the latter for the period 1400-1850). Only after 1850 we see a speeding up decline of d13C in ratio with the emissions.
| Quote: | | (3) When you answered my points 5-8 about Segalstad, your language plus lack of actual evidence makes you sound like the warmists. With this darned climate science, more recent papers do not necessarily do better science than older papers. And Segalstad's collection of papers that show the time CO2 is in the atmosphere to be far less than IPCC want, still hold. And as for there being two different kinds of measurement of CO2 "residence", that sounds like the worst kind of wool-pulling. I need to go back to grasp those notions or non-notions as the case may be. You might be right. But so far I'm not convinced! |
No problem about the residence time, you are not the first (and probably not the last) who doesn't understand the difference between residence time and excess removal time. The first is about the type/quality of what is as CO2 in the atmosphere. The latter about the total amount/quantity. The first decays with 150/800 the latter with 4/800. Quite a difference...
Well, my lack of evidence was more because I had some resistance to repeat my objections: I have written an extensive critique on Jaworowski, where Segalstad was co-writer. Their work was written in 1992 and they obviously haven't read any scientific literature since then, because most of what they wrote was already extensively refuted in 1994, by the work of Etheridge e.a. in the Law Dome ice cores:
http://www.agu.org/pubs/crossref/1996/95JD03410.shtml
This work is only on line for a fee, but I have used parts of it for an extensive comment on Jaworowski (and thus Segalstad) at:
http://www.ferdinand-engelbeen.be/klimaat/jaworowski.html
What for me closed the door of their credibility is that they seems not to know that there is a huge difference between the age of the ice and of the enclosed bubbles. For ice core specialists that is an incredible error.
My opinion on their take of ice core CO2 is sent to Jaworowski (last month) and Segalstad (last week), no reaction until now...
| Quote: | | (4) your photos of the different temperature trends for NH, EQ and SH do not, for me prove your point: they prove mine, that the SH with the higher ocean content is a truer reflection of the steady (inertia-effect) ongoing warming of the oceans that reflects in the steady CO2 rise. Mixing time is sufficient IMO. But again, I need to look at it carefully. |
Have a look at the 1945-1975 difference in trends: the NH cools, the SH warms in the last part, where the SPO/MLO measurements start. The effect of different temperature trends should be visible in the NH-SH CO2 trends, but it isn't... Of course, these are land+ocean temperatures (didn't find ocean only, split in hemispheres) but I don't think that there is much difference, except in slope.
| Quote: | | (5) you haven't even considered the extraordinary fit between my two pictures: local temp anomalies worldwide, and CO2 differential rise |
No, because you are comparing a cumulative increase in the atmosphere with only two points of annual emissions. You need to compare cumulative emissions with cumulative increase... Thus better compare with the data, not the graphs...
The emission data can be found at: http://cdiac.ornl.gov/ftp/ndp030/global.1751_2005.ems
And the lower troposphere temperature - CO2 fit for differences between the NH and the SH is quite short. But even then, see what happens in warming and non-warming (2000-now) periods: nothing happens with the lag, it only gets larger. Again, temperature has very little influence on the trend or the lags between the trends...
| Quote: | (6) nor have you answered the MLO record issues. Nor have you given me access to understanding the diagrams from Quirk.
However, (5) and (6) could be because enough was enough for the time being! and I need to do more homework. Ferdinand, you are hot on this case, following everyone around with your points! Do you know, therefore, who you've had dealings with, who might be most able to help me understand the d13C maths and fractionation experiments and proof? Because I've yet to be convinced that those were done without AGW bias, and though I'm also willing to be convinced, I'd like contact with anyone non-AGW who understands the isotope intricacies.
Enough for now! Cheers  |
What MLO issues? The access to Tom's work is coming...
About isotope changes: see http://www.barrettbellamyclimate.com/page34.htm (Jack Barrett, realistic sceptic...) |
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ian Experienced User
Joined: 02 Sep 2008 Posts: 125 Location: Stirling, South Australia
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Posted: 15 Apr 2009 11:46 am Post subject: |
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Wow, another interesting site...barrett & bellamy, thanks for the link Ferdinand.
best wishes, ian |
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Lucy Skywalker Site Admin

Joined: 09 May 2006 Posts: 535 Location: Somerset, UK
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Posted: 16 Apr 2009 11:25 am Post subject: |
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More work!
Might be more delay for me  |
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Richard111 Experienced User
Joined: 19 Sep 2008 Posts: 420 Location: Pembrokeshire
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Posted: 06 May 2009 07:52 am Post subject: |
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Another inconvenient fact. During ice ages sea levels drop. The sea becomes more salty. The sea cannot now absorb as much CO2. Atmospheric CO2 levels rise.
So why didn't the planet warm up and melt the ice?
The high CO2 levels are there is all the geological ice data. An incontrovertable fact. |
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hqmonaro Experienced User
Joined: 29 Mar 2009 Posts: 81
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Posted: 09 May 2009 02:43 am Post subject: |
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| Richard111 wrote: | Another inconvenient fact. During ice ages sea levels drop. The sea becomes more salty. The sea cannot now absorb as much CO2. Atmospheric CO2 levels rise.
So why didn't the planet warm up and melt the ice?
The high CO2 levels are there is all the geological ice data. An incontrovertable fact. |
The climate is highly complex. Warm oceans actually absorb less CO2 than cold ones.
http://www.aph.gov.au/library/pubs/ClimateChange/theClimate/oceans.htm
There are several forcings at work on the climate, some of which are more powerful than CO2. At present, those other ones aren't as significant as CO2 is. In the future that will change. We have our current problem to deal with, however. |
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PAWB Experienced User

Joined: 14 Oct 2008 Posts: 69 Location: Devon, England
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Posted: 09 May 2009 07:10 pm Post subject: |
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| Quote: | | There are several forcings at work on the climate, some of which are more powerful than CO2. | How very true.
| Quote: | | At present, those other ones aren't as significant as CO2 is. | How do you know the effect of the quiet sun is not as significant as CO2? Many scientists think it is more significant. How do you know water vapour and clouds aren't as significant? Many scientists think they are more significant. How do you know the ocean cycles aren't as significant? Many scientists think they are more significant. _________________ Phillip in Devon, England |
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